| Date | Phase | Home | Away | |||
|---|---|---|---|---|---|---|
| 19/12/2012 | Fifth round | Udinese | | 0-1 | | Fiorentina |
| 19/12/2012 | Fifth round | Napoli | | 1-2 | | Bologna |
| 08/01/2013 | Quarter-finals | Lazio | | 3-0 | | Catania |
| 09/01/2013 | Quarter-finals | Juventus | | 2-1 | | Milan |
| 15/01/2013 | Quarter-finals | Internazionale | | 3-2 | | Bologna |
| 16/01/2013 | Quarter-finals | Fiorentina | | 0-1 | | Roma |
| 22/01/2013 | Semi-finals | Juventus | | 1-1 | | Lazio |
| 23/01/2013 | Semi-finals | Roma | | 2-1 | | Internazionale |
| 29/01/2013 | Semi-finals | Lazio | | 2-1 | | Juventus |
| 17/04/2013 | Semi-finals | Internazionale | | 2-3 | | Roma |