| Date | Phase | Home | Away | |||
|---|---|---|---|---|---|---|
| 12/12/2012 | Fourth round | Aves | | 2-1 | | SC Coimbroes |
| 02/01/2013 | Fifth round | Benfica | | 6-0 | | Aves |
| 16/01/2013 | Quarter-finals | Paços Ferreira | | 2-1 | | Gil Vicente |
| 16/01/2013 | Quarter-finals | Guimarães | | 2-1 | | Braga |
| 17/01/2013 | Quarter-finals | Arouca | | 1-4 | | Belenenses |
| 17/01/2013 | Quarter-finals | Académica | | 0-4 | | Benfica |
| 30/01/2013 | Semi-finals | Paços Ferreira | | 0-2 | | Benfica |
| 27/03/2013 | Semi-finals | Belenenses | | 0-2 | | Guimarães |
| 15/04/2013 | Semi-finals | Benfica | | 1-1 | | Paços Ferreira |
| 17/04/2013 | Semi-finals | Guimarães | | 1-0 | | Belenenses |