Mihajlovic is alleged to have spat at Chelsea forward Adrian Mutu in the 34th minute of the game, which the English side won 4-0. Mihajlovic was later dismissed for a second bookable offence. The allegations will be dealt with by UEFA on Friday 7 November.
In January, UEFA imposed a four-match ban on RC Celta de Vigo midfield player Peter Luccin for spitting at an opponent during the Spanish club's UEFA Cup third round second-leg tie against Celtic FC last December.
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