Grossmüller (Schalke) is cautioned by the referee.
75
Joaquín (in) - Angulo (out) (Valencia)
73
Løvenkrands (in) - Halil Altıntop (out) (Schalke)
73
Grossmüller (in) - Rafinha (out) (Schalke)
69
Bordon (Schalke) is cautioned by the referee.
63
Villa (Valencia) scores! Valencia break the deadlock here in Germany as Luis Miguel pings a long ball forward from deep in the Schalke half towards David Villa, who outpaces Heiko Westermann and evades the challenge of goalkeeper Manuel Neuer to sidefoot in from a tight angle. It is the Spanish international's fifth UEFA Champions League goal in what is only his tenth appearance.