 |  |
| 25 |  | Pepe Reina (GK) |
| | 1 |  | Olexandr Shovkovskiy (GK) (C) |
| |
| 2 |  | Gonzalo Rodríguez |
| | 4 |  | Rodolfo |
| |
| 3 |  | Rodolfo Arruabarrena |
| | 7 |  | Jerko Leko |
|  51 |
| 4 |  | Santi Cazorla |
|  31 | 9 |  | Kleber |
| |
| 8 |  | Juan Riquelme |
| | 13 |  | Goran Sabljić |
| |
| 12 |  | Juan Pablo Sorín |
|  5181 | 15 |  | Diogo Rincón |
| |
| 15 |  | Luciano Figueroa |
| 20 60 | 20 |  | Oleh Gusev |
| |
| 16 |  | Quique Álvarez (C) |
| | 23 |  | Māris Verpakovskis |
| 46 |
| 17 |  | Javi Venta |
| | 26 |  | Andriy Nesmachniy |
| 57 |
| 19 |  | Marcos Senna |
| | 32 |  | Goran Gavrančić |
| |
| 23 |  | José Marí |
| 75 | 37 |  | Ayila Yussuf |
| |
Substitutes |
| 1 |  | Javier Vallejo (GK) |
| | 21 |  | Vitaliy Reva (GK) |
| |
| 6 |  | Josico |
| 60 | 6 |  | Yuriy Dmytrulin |
| |
| 7 |  | Antonio Guayre |
| 75 | 8 |  | Valentin Belkevich |
| |
| 11 |  | Javier Calleja |
| | 10 |  | Florin Cernat |
| 51 |
| 14 |  | Héctor Font |
| 81 | 11 |  | Georgi Peev |
| |
| 38 |  | Edu |
| | 16 |  | Maksim Shatskikh |
| 46 |
| 41 |  | González Rubén |
| | 30 |  | Badr El Kaddouri |
| 57 |
Coach |
| Manuel Pellegrini (CHI) | | | Jochef Sabo (UKR) | |
Referee |
| Matthew David Messias (ENG) |
Assistant referees |
| Kevin Pike (ENG), Roger East (ENG) |
Fourth official |
| Howard Webb (ENG) |
Own goal
Penalties
Missed Penalties
Red Cards
Yellow/red card