Dnipro Arena - Dnipropetrovsk 20/09/2012 - 19:00CET (20:00 local time)
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| 2-0 | |

FC Dnipro Dnipropetrovsk got their UEFA Europa League campaign off to a fine start by capitalising on a pair of defensive errors to beat PSV Eindhoven at the Dnipro Arena.
After a first half of few opportunities, the hosts took control in the second period, scoring twice in an eight-minute spell. Brazilian striker Matheus netted the opener with an opportunistic header before Atiba Hutchinson's own goal ensured that PSV return to the Netherlands empty-handed.
Dnipro | PSV | ||
| 16 | Laštůvka (GK) | 21 | Waterman (GK) |
| 3 | Mazuch | 4 | Marcelo |
| 5 | Mandziuk | 6 | Van Bommel (C) |
| 8 | Giuliano | 7 | Toivonen |
| 10 | Konoplyanka | 8 | Strootman |
| 14 | Cheberyachko | 11 | Lens |
| 17 | Strinić | 13 | Hutchinson |
| 18 | Zozulya | 14 | Mertens |
| 21 | Seleznyov | 15 | Willems |
| 29 | Rotan (C) | 17 | Narsingh |
| 99 | Matheus | 18 | Derijck |
Substitutes | |||
| 77 | Shelikhov (GK) | 1 | Tytoń (GK) |
| 4 | Kravchenko | 2 | Jørgensen |
| 6 | Kankava | 9 | Matavž |
| 9 | Kalinić | 10 | Wijnaldum |
| 19 | Denisov | 16 | Engelaar |
| 23 | Odibe | 22 | Depay |
| 88 | Aliyev | 23 | Manolev |
Coaches | |||
| Juande Ramos (ESP) | Dick Advocaat (NED) | ||
Referee | |||
| Miroslav Zelinka (CZE) | |||
Legend:
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Full-time at the Dnipro Arena. Juande Ramos's side begin their UEFA Europa League campaign with a ruthless win over PSV.