Matches
14 August 2021
Alavés
1-4
-
Real Madrid
21 August 2021
Alavés
0-1
-
Mallorca
27 August 2021
Valencia
3-0
-
Alavés
11 September 2021
Villarreal
-
-
Alavés
Match postponed
18 September 2021
Alavés
0-2
-
Osasuna
22 September 2021
Espanyol
1-0
-
Alavés
25 September 2021
Alavés
-
-
Atlético
01 October 2021
Athletic Club
-
-
Alavés
18 October 2021
Alavés
-
-
Betis
24 October 2021
Cádiz
-
-
Alavés
27 October 2021
Alavés
-
-
Elche
31 October 2021
Barcelona
-
-
Alavés
07 November 2021
Alavés
-
-
Levante
21 November 2021
Sevilla
-
-
Alavés
28 November 2021
Alavés
-
-
Celta
05 December 2021
Granada
-
-
Alavés
12 December 2021
Alavés
-
-
Getafe
19 December 2021
Rayo Vallecano
-
-
Alavés
02 January 2022
Alavés
-
-
Real Sociedad
09 January 2022
Alavés
-
-
Athletic Club
19 January 2022
Betis
-
-
Alavés
23 January 2022
Alavés
-
-
Barcelona
06 February 2022
Elche
-
-
Alavés
13 February 2022
Alavés
-
-
Valencia
20 February 2022
Real Madrid
-
-
Alavés
27 February 2022
Getafe
-
-
Alavés
06 March 2022
Alavés
-
-
Sevilla
13 March 2022
Real Sociedad
-
-
Alavés
20 March 2022
Alavés
-
-
Granada
03 April 2022
Atlético
-
-
Alavés
10 April 2022
Osasuna
-
-
Alavés
17 April 2022
Alavés
-
-
Rayo Vallecano
20 April 2022
Mallorca
-
-
Alavés
01 May 2022
Alavés
-
-
Villarreal
08 May 2022
Celta
-
-
Alavés
11 May 2022
Alavés
-
-
Espanyol
15 May 2022
Levante
-
-
Alavés
22 May 2022
Alavés
-
-
Cádiz