Champions Paris Saint-Germain kicked off their title defence in style by dispatching Atalanta 4-0 at the Parc des Princes, with goals from Marquinhos, Khvicha Kvaratskhelia, Nuno Mendes and Gonçalo Ramos. At Anfield, Liverpool left it late again to grab all three points, with defender Virgil van Dijk heading in an added-time winner to seal a 3-2 victory over Atleti. In Munich, Bayern saw off Chelsea 3-1, thanks to another brace from their top scorer Harry Kane. We hear from the UEFA Player of The Match in all three matches, Paris winger Kvaratskhelia, Liverpool captain Van Dijk and Bayern match winner Kane, as well as Reds defender Andy Robertson.Elsewhere, Inter overcame Ajax 2-0 in Amsterdam, Marcus Thuram with both goals, and we hear from one of the Italian side's new signings, defender Manuel Akanji.In the evening's early kick-offs, Bodø/Glimt came back from 2-0 down to earn a hard-fought point at Slavia Praha and Olympiacos were impressively held 0-0 at home by Cypriot Champions League debutants Pafos – we get reaction from their defender and Player of the Match Derrick Luckassen.Plus we look ahead to the final night of Matchday 1 action, with another six games taking place across Europe on Thursday evening, including our featured commentary match Newcastle vs Barcelona and Manchester City vs Napoli with the thoughts of Pep Guardiola.