The draw came less than a month after Liverpool were crowned European champions by beating AC Milan on penalties after a 3-3 draw in Istanbul. The English side were given special dispensation to enter the competition at this stage, despite finishing fifth in the English Premiership last season.
Should they progress against the Welsh champions in next month's two-legged tie, Liverpool will play either HB Tórshavn of the Faroe Islands or FBK Kaunas of Lithuania in the second qualifying round, the draw for which was also made today.
'Couldn't be better'
Liverpool chief executive Rick Parry said he was "pleased" to be taking on TNS "because it's not too far to travel". He added: "It couldn't be better in that respect - we didn't want to be travelling to the far reaches of Europe or the borders of Asia, so we've ended up quite lucky with this one.
'Doing our homework'
"Again, logistically, it could be worse for the second qualifying round," Parry continued. "We're doing our homework at the moment, the teams are unknown quantities to us at the minute."
Meanwhile, TNS general manager Ian Williams was understandably delighted with the draw, saying: "We gave a huge cheer when our name came out. It'll raise the profile of the club internationally and nationally, and obviously financially it's going to reward us as well. When our name came out it was absolutely fantastic.
'Chance of winning'
"Having Liverpool is the glamour of the Champions League - from a profile point of view, it gives us massive publicity not just for our club but for Welsh football in general. There's always a chance of winning - it's two games, 180 minutes, and the nature of the game is that either side can win."
Romualdas Kontrimas, executive director of Lithuanian champions Kaunas, had one eye on a Liverpool victory to complement a win for his club against HB Tórshavn, when he said: "A club of such stature has never travelled to Lithuania before. But in the first round we face a familiar opponent in HB, who we played in 2003 at the same stage and won 5-1 against."
Another intriguing tie at the second-round stage is FC Dynamo Kyiv of Ukraine against Switzerland's FC Thun. There is also the prospect of Glentoran FC of Northern Ireland meeting their counterparts Shelbourne FC from the Republic in the previous round.
The first qualifying round takes place over two legs on 12/13 and 19/20 July, with the second qualifying round following on 26/27 July and 2/3 August. The draw for the third qualifying round will be made at 12.00CET in Nyon on 29 July. The final is set for 17 May 2006 at the Stade de France, Paris.
©UEFA.com 1998-2014. All rights reserved.